1.
Which chloro derivative undergoes hydrolysis most readily with aq. NaOH?
2.
Phenol + CHCl₃ + alc. KOH → salicylaldehyde. Name reaction?
4.
Which compound shows metamerism?
5.
Ether cleavage with HI → major products?
6.
Phenyl-methyl ether + HI → ?
7.
Alcohol + base + alkyl halide → ether. This is:
8.
CH₃)₃CONa + CH₃CHClCH₃ → ether. Reaction name?
9.
CH₃CH=CHCH₃ + HBr/H₂O₂ → Y; Y + CH₃CH₂ONa → Z. Find Z.
10.
Reactants to produce anisole (Ph–OCH₃)?
11.
Which ether gives methanol with hot conc. HI?
12.
Mixed ether + HI → what product?
13.
CH₃OCH(CH₃)₂ + HI → ?
14.
Ethanol has higher boiling point than dimethyl ether because of?
15.
Sodium phenoxide + ethyl iodide → ?
16.
Anisole + excess HI → ?
17.
Match the reaction types: A-D with processes
18.
Acetone + CH₃MgBr → product after hydrolysis?
19.
Benzaldehyde + acetophenone + NaOH → reaction name?
20.
Compound A in Rosenmund reaction?
21.
Cyclohexanone undergoes aldol condensation + heating → product?
22.
Identify A, X, Y, Z from multi-step reaction: Alcohol → Aldehyde → Aldol → Derivative
23.
Aldehyde + primary amine → ?
24.
Cyclopentanone + CH₃Li → intermediate formed?
25.
Which of the following compounds can exhibit tautomerism?
26.
Compound X (C₅H₁₀O) gives phenylhydrazone, negative iodoform and Tollen's test, and gives n-pentane on reduction. X is?
27.
Reaction of carbonyl compound with which reagent involves nucleophilic addition followed by elimination of water?
28.
Oxidation of benzene with V₂O₅ in air gives?
29.
Reaction by which benzaldehyde cannot be prepared?
30.
CH₃CHO vs C₆H₅CH₂CHO: Which test distinguishes them?
31.
Acetone + excess ethanol + HCl gives?
32.
Clemmensen reduction of ketone is done using?
33.
A strong base can abstract an α-hydrogen from?
34.
Product of aldol condensation?
35.
Compound that gives alcohol and acid with 50% NaOH?
36.
Reduction of carbonyl to alkane using Zn(Hg)/HCl is called?
37.
Compound most reactive in nucleophilic addition?
38.
Carbonyl compound + HCN → cyanohydrin → racemic α-hydroxy acid?
39.
Which can be oxidised to carbonyl compound?
40.
CH₃CHO + HCN → cyanohydrin → α-hydroxy acid: stereoisomer product?
41.
NaBH₄ reduces CH₃COOCH₂CH₃ → ?
42.
Identify X: CHCl₃ + hv → ? then hydrolysis at 373K
43.
HC≡CCH₃ + H₂O, Hg²⁺/H⁺ → intermediate + product?
44.
Identify the product A in selective hydrogenation of α,β-unsaturated carbonyl compound
45.
Ozonolysis gives single compound. Which cyclic compound gives it?
